I was informed by Mrs. B. about the Museum of New York's photo archives when she sent me the following picture asking if I knew what church it was. I was pretty sure it was St. John's Episcopal in Rosebank. It took a little digging to decide that it absolutely was St. John's. I checked present day images of the church on its own website, looked at the old maps to see if there was a house next to the church in the past (there was; a G.S. Schofield lived there), and finally drove past the church to do one last double check. I was right.
On June 1, 1895, Miss Anne Flemming Cameron, third daughter of Sir Roderick Cameron, married Mr. Belmont Tiffany, grandson of Commodore Matthew C. Perry, at St. John's Episcopal Church in Rosebank, Staten Island. Following the wedding they took carriages to the bride's father's 130-acre country estate in Arrochar, "Clifton Berley".
The Bride's Arrival at St. John's Episcopal Church
A little more digging turned up the following article from the New York Times on May 17, 1895. One of the things I've learned in digging into the history of Staten Island's golden age is that the very wealthy were very well documented.
Above - The Bride's Carriage Returns - Right - The church today
The Bride's Departure
Wedding Reception Photos - presumably this is at "Clifton Berley".
Further research told me that the couple divorce and both outlived their only son, George. Belmont ended up in the papers when he was sued by widow for failing to live up to his promise to marry her. Mrs. Tiffany became a noted society decorator and decorate the Astor Estate on Bermuda. Later both ended up in the papers again when it seemed their son was arrested for drug addiction and committed to the Bloomingdale Hospital for the Insane.